A colloid is a mixture in which one substance of microscopically dispersed insoluble particles are suspended throughout another substance. However, some definitions specify that the particles must be dispersed in a liquid, and others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture (although a narrower sense of the word suspension is distinguished from colloids by larger particle size). A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre.
Colloidal suspensions are the subject of interface and colloid science. This field of study was introduced in 1845 by Italian chemist Francesco Selmi and further investigated since 1861 by Scottish scientist Thomas Graham.
Colloids can be classified as follows:
|Gas||No such colloids are known.
Helium and xenon are known to be immiscible under certain conditions.
Examples: fog, clouds, condensation, mist,steam,hair sprays
Examples: smoke, ice cloud, atmospheric particulate matter
Example: whipped cream, shaving cream
|Emulsion or Liquid crystal
Examples: milk, mayonnaise, hand cream, latex, biological membranes, liquid biomolecular condensate
|Sol or suspension|
Examples: pigmented ink, sediment, precipitates, solid biomolecular condensate
Examples: aerogel, styrofoam, pumice
Examples: agar, gelatin, jelly, gel-like biomolecular condensate
Example: cranberry glass
Homogeneous mixtures with a dispersed phase in this size range may be called colloidal aerosols, colloidal emulsions, colloidal foams, colloidal dispersions, or hydrosols.
Colloid compared with solution
A colloid has a dispersed phase and a continuous phase, whereas in a solution, the solute and solvent constitute only one phase. A solute in a solution are individual molecules or ions, whereas colloidal particles are bigger. For example, in a solution of salt in water, the sodium chloride (NaCl) crystal dissolves, and the Na+ and Cl− ions are surrounded by water molecules. However, in a colloid such as milk, the colloidal particles are globules of fat, rather than individual fat molecules.
Interaction between particles
- Excluded volume repulsion: This refers to the impossibility of any overlap between hard particles.
- Electrostatic interaction: Colloidal particles often carry an electrical charge and therefore attract or repel each other. The charge of both the continuous and the dispersed phase, as well as the mobility of the phases are factors affecting this interaction.
- van der Waals forces: This is due to interaction between two dipoles that are either permanent or induced. Even if the particles do not have a permanent dipole, fluctuations of the electron density gives rise to a temporary dipole in a particle. This temporary dipole induces a dipole in particles nearby. The temporary dipole and the induced dipoles are then attracted to each other. This is known as van der Waals force, and is always present (unless the refractive indexes of the dispersed and continuous phases are matched), is short-range, and is attractive.
- Steric forces between polymer-covered surfaces or in solutions containing non-adsorbing polymer can modulate interparticle forces, producing an additional steric repulsive force (which is predominantly entropic in origin) or an attractive depletion force between them.
The Earth’s gravitational field acts upon colloidal particles. Therefore, if the colloidal particles are denser than the medium of suspension, they will sediment (fall to the bottom), or if they are less dense, they will cream (float to the top). Larger particles also have a greater tendency to sediment because they have smaller Brownian motion to counteract this movement.
is the Archimedean weight of the colloidal particles,
is the viscosity of the suspension medium,
is the radius of the colloidal particle,
and is the sedimentation or creaming velocity.
The mass of the colloidal particle is found using:
is the volume of the colloidal particle, calculated using the volume of a sphere ,
and is the difference in mass density between the colloidal particle and the suspension medium.
By rearranging, the sedimentation or creaming velocity is:
There is an upper size-limit for the diameter of colloidal particles because particles larger than 1 μm tend to sediment, and thus the substance would no longer be considered a colloidal suspension.
The colloidal particles are said to be in sedimentation equilibrium if the rate of sedimentation is equal to the rate of movement from Brownian motion.
There are two principal ways to prepare colloids:
- Dispersion of large particles or droplets to the colloidal dimensions by milling, spraying, or application of shear (e.g., shaking, mixing, or high shear mixing).
- Condensation of small dissolved molecules into larger colloidal particles by precipitation, condensation, or redox reactions. Such processes are used in the preparation of colloidal silica or gold.
The stability of a colloidal system is defined by particles remaining suspended in solution and depends on the interaction forces between the particles. These include electrostatic interactions and van der Waals forces, because they both contribute to the overall free energy of the system.
A colloid is stable if the interaction energy due to attractive forces between the colloidal particles is less than kT, where k is the Boltzmann constant and T is the absolute temperature. If this is the case, then the colloidal particles will repel or only weakly attract each other, and the substance will remain a suspension.
If the interaction energy is greater than kT, the attractive forces will prevail, and the colloidal particles will begin to clump together. This process is referred to generally as aggregation, but is also referred to as flocculation, coagulation or precipitation. While these terms are often used interchangeably, for some definitions they have slightly different meanings. For example, coagulation can be used to describe irreversible, permanent aggregation where the forces holding the particles together are stronger than any external forces caused by stirring or mixing. Flocculation can be used to describe reversible aggregation involving weaker attractive forces, and the aggregate is usually called a floc. The term precipitation is normally reserved for describing a phase change from a colloid dispersion to a solid (precipitate) when it is subjected to a perturbation. Aggregation causes sedimentation or creaming, therefore the colloid is unstable: if either of these processes occur the colloid will no longer be a suspension.
Electrostatic stabilization and steric stabilization are the two main mechanisms for stabilization against aggregation.
- Electrostatic stabilization is based on the mutual repulsion of like electrical charges. The charge of colloidal particles is structured in an electrical double layer, where the particles are charged on the surface, but then attract counterions (ions of opposite charge) which surround the particle. The electrostatic repulsion between suspended colloidal particles is most readily quantified in terms of the zeta potential. The combined effect of van der Waals attraction and electrostatic repulsion on aggregation is described quantatively by the DLVO theory. A common method of stabilising a colloid (converting it from a precipitate) is peptization, a process where it is shaken with an electrolyte.
- Steric stabilization consists absorbing a layer of a polymer or surfactant on the particles to prevent them from getting close in the range of attractive forces. The polymer consists of chains that are attached to the particle surface, and the part of the chain that extends out is soluble in the suspension medium. This technique is used to stabilize colloidal particles in all types of solvents, including organic solvents.
A combination of the two mechanisms is also possible (electrosteric stabilization).
A method called gel network stabilization represents the principal way to produce colloids stable to both aggregation and sedimentation. The method consists in adding to the colloidal suspension a polymer able to form a gel network. Particle settling is hindered by the stiffness of the polymeric matrix where particles are trapped, and the long polymeric chains can provide a steric or electrosteric stabilization to dispersed particles. Examples of such substances are xanthan and guar gum.
Destabilization can be accomplished by different methods:
- Removal of the electrostatic barrier that prevents aggregation of the particles. This can be accomplished by the addition of salt to a suspension to reduce the Debye screening length (the width of the electrical double layer) of the particles. It is also accomplished by changing the pH of a suspension to effectively neutralise the surface charge of the particles in suspension. This removes the repulsive forces that keep colloidal particles separate and allows for aggregation due to van der Waals forces. Minor changes in pH can manifest in significant alteration to the zeta potential. When the magnitude of the zeta potential lies below a certain threshold, typically around ± 5mV, rapid coagulation or aggregation tends to occur.
- Addition of a charged polymer flocculant. Polymer flocculants can bridge individual colloidal particles by attractive electrostatic interactions. For example, negatively charged colloidal silica or clay particles can be flocculated by the addition of a positively charged polymer.
- Addition of non-adsorbed polymers called depletants that cause aggregation due to entropic effects.
Unstable colloidal suspensions of low-volume fraction form clustered liquid suspensions, wherein individual clusters of particles sediment if they are more dense than the suspension medium, or cream if they are less dense. However, colloidal suspensions of higher-volume fraction form colloidal gels with viscoelastic properties. Viscoelastic colloidal gels, such as bentonite and toothpaste, flow like liquids under shear, but maintain their shape when shear is removed. It is for this reason that toothpaste can be squeezed from a toothpaste tube, but stays on the toothbrush after it is applied.
The most widely used technique to monitor the dispersion state of a product, and to identify and quantify destabilization phenomena, is multiple light scattering coupled with vertical scanning. This method, known as turbidimetry, is based on measuring the fraction of light that, after being sent through the sample, it backscattered by the colloidal particles. The backscattering intensity is directly proportional to the average particle size and volume fraction of the dispersed phase. Therefore, local changes in concentration caused by sedimentation or creaming, and clumping together of particles caused by aggregation, are detected and monitored. These phenomena are associated with unstable colloids.
Dynamic light scattering can be used to detect the size of a colloidal particle by measuring how fast they diffuse. This method involves directing laser light towards a colloid. The scattered light will form an interference pattern, and the fluctuation in light intensity in this pattern is caused by the Brownian motion of the particles. If the apparent size of the particles increases due to them clumping together via aggregation, it will result in slower Brownian motion. This technique can confirm that aggregation has occurred if the apparent particle size is determined to be beyond the typical size range for colloidal particles.
Accelerating methods for shelf life prediction
The kinetic process of destabilisation can be rather long (up to several months or even years for some products) and it is often required for the formulator to use further accelerating methods in order to reach reasonable development time for new product design. Thermal methods are the most commonly used and consists in increasing temperature to accelerate destabilisation (below critical temperatures of phase inversion or chemical degradation). Temperature affects not only the viscosity, but also interfacial tension in the case of non-ionic surfactants or more generally interactions forces inside the system. Storing a dispersion at high temperatures enables to simulate real life conditions for a product (e.g. tube of sunscreen cream in a car in the summer), but also to accelerate destabilisation processes up to 200 times. Mechanical acceleration including vibration, centrifugation and agitation are sometimes used. They subject the product to different forces that pushes the particles / droplets against one another, hence helping in the film drainage. However, some emulsions would never coalesce in normal gravity, while they do under artificial gravity. Moreover, segregation of different populations of particles have been highlighted when using centrifugation and vibration.
As a model system for atoms
In physics, colloids are an interesting model system for atoms. Micrometre-scale colloidal particles are large enough to be observed by optical techniques such as confocal microscopy. Many of the forces that govern the structure and behavior of matter, such as excluded volume interactions or electrostatic forces, govern the structure and behavior of colloidal suspensions. For example, the same techniques used to model ideal gases can be applied to model the behavior of a hard sphere colloidal suspension. In addition, phase transitions in colloidal suspensions can be studied in real time using optical techniques, and are analogous to phase transitions in liquids. In many interesting cases optical fluidity is used to control colloid suspensions.
A colloidal crystal is a highly ordered array of particles that can be formed over a very long range (typically on the order of a few millimeters to one centimeter) and that appear analogous to their atomic or molecular counterparts. One of the finest natural examples of this ordering phenomenon can be found in precious opal, in which brilliant regions of pure spectral color result from close-packed domains of amorphous colloidal spheres of silicon dioxide (or silica, SiO2). These spherical particles precipitate in highly siliceous pools in Australia and elsewhere, and form these highly ordered arrays after years of sedimentation and compression under hydrostatic and gravitational forces. The periodic arrays of submicrometre spherical particles provide similar arrays of interstitial voids, which act as a natural diffraction grating for visible light waves, particularly when the interstitial spacing is of the same order of magnitude as the incident lightwave.
Thus, it has been known for many years that, due to repulsive Coulombic interactions, electrically charged macromolecules in an aqueous environment can exhibit long-range crystal-like correlations with interparticle separation distances, often being considerably greater than the individual particle diameter. In all of these cases in nature, the same brilliant iridescence (or play of colors) can be attributed to the diffraction and constructive interference of visible lightwaves that satisfy Bragg’s law, in a matter analogous to the scattering of X-rays in crystalline solids.
The large number of experiments exploring the physics and chemistry of these so-called "colloidal crystals" has emerged as a result of the relatively simple methods that have evolved in the last 20 years for preparing synthetic monodisperse colloids (both polymer and mineral) and, through various mechanisms, implementing and preserving their long-range order formation.
Colloidal phase separation is an important organising principle for compartmentalisation of both the cytoplasm and nucleus of cells into biomolecular condensates, similar in importance to compartmentalisation via lipid bilayer membranes - a type of liquid crystal. The term biomolecular condensate has been used to refer to clusters of macromolecules that arise via liquid-liquid or liquid-solid phase separation within cells. Macromolecular crowding strongly enhances colloidal phase separation and formation of biomolecular condensates.
In the environment
Colloidal particles can also serve as transport vector of diverse contaminants in the surface water (sea water, lakes, rivers, fresh water bodies) and in underground water circulating in fissured rocks (e.g. limestone, sandstone, granite). Radionuclides and heavy metals easily sorb onto colloids suspended in water. Various types of colloids are recognised: inorganic colloids (e.g. clay particles, silicates, iron oxy-hydroxides), organic colloids (humic and fulvic substances). When heavy metals or radionuclides form their own pure colloids, the term "eigencolloid" is used to designate pure phases, i.e., pure Tc(OH)4, U(OH)4, or Am(OH)3. Colloids have been suspected for the long-range transport of plutonium on the Nevada Nuclear Test Site. They have been the subject of detailed studies for many years. However, the mobility of inorganic colloids is very low in compacted bentonites and in deep clay formations because of the process of ultrafiltration occurring in dense clay membrane. The question is less clear for small organic colloids often mixed in porewater with truly dissolved organic molecules.
In soil science, the colloidal fraction in soils consists of tiny clay and humus particles that are less than 1μm in diameter and carry either positive and/or negative electrostatic charges that vary depending on the chemical conditions of the soil sample, i.e. soil pH.
Colloid solutions used in intravenous therapy belong to a major group of volume expanders, and can be used for intravenous fluid replacement. Colloids preserve a high colloid osmotic pressure in the blood, and therefore, they should theoretically preferentially increase the intravascular volume, whereas other types of volume expanders called crystalloids also increase the interstitial volume and intracellular volume. However, there is still controversy to the actual difference in efficacy by this difference, and much of the research related to this use of colloids is based on fraudulent research by Joachim Boldt. Another difference is that crystalloids generally are much cheaper than colloids.
- Israelachvili, Jacob N. (2011). Intermolecular and surface forces (3rd ed.). Burlington, MA: Academic Press. ISBN 978-0-08-092363-5. OCLC 706803091.
- International Union of Pure and Applied Chemistry. Subcommittee on Polymer Terminology (2009). Compendium of polymer terminology and nomenclature : IUPAC recommendations, 2008. Richard G. Jones, International Union of Pure and Applied Chemistry. Commission on Macromolecular Nomenclature. Cambridge: Royal Society of Chemistry. ISBN 978-1-84755-942-5. OCLC 406528399.
- Stepto, Robert F. T. (1 January 2009). "Dispersity in polymer science (IUPAC Recommendations 2009)". Pure and Applied Chemistry. 81 (2): 351–353. doi:10.1351/PAC-REC-08-05-02. ISSN 1365-3075. S2CID 95122531.
- Francesco Selmi, Studi sulla dimulsione di cloruro d'argento, Nuovi Annali delle Scienze Naturali di Bologna, fasc. di agosto 1845.
- Graham coined the term "colloid" in 1861. See: Graham, Thomas (1861) "Liquid diffusion applied to analysis", Philosophical Transactions of the Royal Society of London, 151 : 183–224. From page 183: "As gelatine appears to be its type, it is proposed to designate substances of the class as colloids, and to speak of their peculiar form of aggregation as the colloidal condition of matter."
- Richard G. Jones; Edward S. Wilks; W. Val Metanomski; Jaroslav Kahovec; Michael Hess; Robert Stepto; Tatsuki Kitayama, eds. (2009). Compendium of Polymer Terminology and Nomenclature (IUPAC Recommendations 2008) (2nd ed.). RSC Publ. p. 464. ISBN 978-0-85404-491-7.
- Stepto, Robert F. T. (2009). "Dispersity in polymer science (IUPAC Recommendations 2009)" (PDF). Pure and Applied Chemistry. 81 (2): 351–353. doi:10.1351/PAC-REC-08-05-02. S2CID 95122531.
- Slomkowski, Stanislaw; Alemán, José V.; Gilbert, Robert G.; Hess, Michael; Horie, Kazuyuki; Jones, Richard G.; Kubisa, Przemyslaw; Meisel, Ingrid; Mormann, Werner; Penczek, Stanisław; Stepto, Robert F. T. (2011). "Terminology of polymers
and polymerization processes in dispersed systems (IUPAC Recommendations 2011)" (PDF). Pure and Applied Chemistry. 83 (12): 2229–2259. doi:10.1351/PAC-REC-10-06-03. S2CID 96812603.
- de Swaan Arons, J.; Diepen, G. A. M. (2010). "Immiscibility of gases. The system He-Xe: (Short communication)". Recueil des Travaux Chimiques des Pays-Bas. 82 (8): 806. doi:10.1002/recl.19630820810. ISSN 0165-0513.
- de Swaan Arons, J.; Diepen, G. A. M. (1966). "Gas—Gas Equilibria". J. Chem. Phys. 44 (6): 2322. Bibcode:1966JChPh..44.2322D. doi:10.1063/1.1727043.
- Lekkerkerker, Henk N.W.; Tuinier, Remco (2011). Colloids and the Depletion Interaction. Heidelberg: Springer. doi:10.1007/978-94-007-1223-2. ISBN 9789400712225. Archived from the original on 14 April 2019. Retrieved 5 September 2018.
- van Anders, Greg; Klotsa, Daphne; Ahmed, N. Khalid; Engel, Michael; Glotzer, Sharon C. (2014). "Understanding shape entropy through local dense packing". Proc Natl Acad Sci USA. 111 (45): E4812–E4821. arXiv:1309.1187. Bibcode:2014PNAS..111E4812V. doi:10.1073/pnas.1418159111. PMC 4234574. PMID 25344532.
- Cosgrove, Terence (2010). Colloid Science: Principles, Methods and Applications. John Wiley & Sons. ISBN 9781444320183.
- Kopeliovich, Dmitri. Preparation of colloids. substech.com
- Everett, D. H. (1988). Basic principles of colloid science. London: Royal Society of Chemistry. ISBN 978-1-84755-020-0. OCLC 232632488.
- Slomkowski, Stanislaw; Alemán, José V.; Gilbert, Robert G.; Hess, Michael; Horie, Kazuyuki; Jones, Richard G.; Kubisa, Przemyslaw; Meisel, Ingrid; Mormann, Werner; Penczek, Stanisław; Stepto, Robert F. T. (10 September 2011). "Terminology of polymers and polymerization processes in dispersed systems (IUPAC Recommendations 2011)". Pure and Applied Chemistry (in German). 83 (12): 2229–2259. doi:10.1351/PAC-REC-10-06-03. ISSN 1365-3075. S2CID 96812603.
- Park, Soo-Jin; Seo, Min-Kang (1 January 2011). "Intermolecular Force". Interface Science and Technology. 18: 1–57. doi:10.1016/B978-0-12-375049-5.00001-3. ISBN 9780123750495. ISSN 1573-4285.
- Colloid stability : the role of surface forces. Part I. Tharwat F. Tadros. Weinheim: Wiley-VCH. 2007. ISBN 978-3-527-63107-0. OCLC 701308697.CS1 maint: others (link)
- Genz, Ulrike; D'Aguanno, Bruno; Mewis, Jan; Klein, Rudolf (1 July 1994). "Structure of Sterically Stabilized Colloids". Langmuir. 10 (7): 2206–2212. doi:10.1021/la00019a029. ISSN 0743-7463.
- Comba, Silvia; Sethi (August 2009). "Stabilization of highly concentrated suspensions of iron nanoparticles using shear-thinning gels of xanthan gum". Water Research. 43 (15): 3717–3726. doi:10.1016/j.watres.2009.05.046. PMID 19577785.
- Bean, Elwood L.; Campbell, Sylvester J.; Anspach, Frederick R.; Ockershausen, Richard W.; Peterman, Charles J. (1964). "Zeta Potential Measurements in the Control of Coagulation Chemical Doses [with Discussion]". Journal (American Water Works Association). 56 (2): 214–227. doi:10.1002/j.1551-8833.1964.tb01202.x. ISSN 0003-150X. JSTOR 41264141.
- Roland, I; Piel, G; Delattre, L; Evrard, B (2003). "Systematic characterisation of oil-in-water emulsions for formulation design". International Journal of Pharmaceutics. 263 (1–2): 85–94. doi:10.1016/S0378-5173(03)00364-8. PMID 12954183.
- Lemarchand, Caroline; Couvreur, Patrick; Besnard, Madeleine; Costantini, Dominique; Gref, Ruxandra (2003). "Novel polyester-polysaccharide nanoparticles". Pharmaceutical Research. 20 (8): 1284–92. doi:10.1023/A:1025017502379. PMID 12948027. S2CID 24157992.
- Mengual, O (1999). "Characterisation of instability of concentrated dispersions by a new optical analyser: the TURBISCAN MA 1000". Colloids and Surfaces A: Physicochemical and Engineering Aspects. 152 (1–2): 111–123. doi:10.1016/S0927-7757(98)00680-3.
- Bru, P.; et al. (2004). T. Provder; J. Texter (eds.). Particle sizing and characterisation.
- Matusiak, Jakub; Grządka, Elżbieta (8 December 2017). "Stability of colloidal systems - a review of the stability measurements methods". Annales Universitatis Mariae Curie-Sklodowska, sectio AA – Chemia. 72 (1): 33. doi:10.17951/aa.2017.72.1.33. ISSN 2083-358X.
- Salager, J-L (2000). Françoise Nielloud; Gilberte Marti-Mestres (eds.). Pharmaceutical emulsions and suspensions. CRC press. p. 89. ISBN 978-0-8247-0304-2.
- Snabre, Patrick; Pouligny, Bernard (2008). "Size Segregation in a Fluid-like or Gel-like Suspension Settling under Gravity or in a Centrifuge". Langmuir. 24 (23): 13338–47. doi:10.1021/la802459u. PMID 18986182.
- Manoharan, Vinothan N. (2015). "Colloidal matter: Packing, geometry, and entropy" (PDF). Science. 349 (6251): 1253751. doi:10.1126/science.1253751. PMID 26315444. S2CID 5727282.
- Greenfield, Elad; Nemirovsky, Jonathan; El-Ganainy, Ramy; Christodoulides, Demetri N; Segev, Mordechai (2013). "Shockwave based nonlinear optical manipulation in densely scattering opaque suspensions". Optics Express. 21 (20): 23785–23802. Bibcode:2013OExpr..2123785G. doi:10.1364/OE.21.023785. PMID 24104290.
- Greenfield, Elad; Rotschild, Carmel; Szameit, Alexander; Nemirovsky, Jonathan; El-Ganainy, Ramy; Christodoulides, Demetrios N; Saraf, Meirav; Lifshitz, Efrat; Segev, Mordechai (2011). "Light-induced self-synchronizing flow patterns". New Journal of Physics. 13 (5): 053021. Bibcode:2011NJPh...13e3021G. doi:10.1088/1367-2630/13/5/053021.
- Pieranski, P. (1983). "Colloidal Crystals". Contemporary Physics. 24: 25–73. Bibcode:1983ConPh..24...25P. doi:10.1080/00107518308227471.
- Sanders, J.V.; Sanders, J. V.; Segnit, E. R. (1964). "Structure of Opal". Nature. 204 (4962): 1151. Bibcode:1964Natur.204..990J. doi:10.1038/204990a0. S2CID 4191566.
- Darragh, P.J.; et al. (1976). "Opals". Scientific American. 234 (4): 84–95. Bibcode:1976SciAm.234d..84D. doi:10.1038/scientificamerican0476-84.
- Luck, Werner; Klier, Manfred; Wesslau, Hermann (1963). "Über Bragg-Reflexe mit sichtbarem Licht an monodispersen Kunststofflatices. II". Berichte der Bunsengesellschaft für Physikalische Chemie. 67 (1): 84–85. doi:10.1002/bbpc.19630670114.
- Hiltner, P.A.; Krieger, I.M. (1969). "Diffraction of light by ordered suspensions". J. Phys. Chem. 73 (7): 2306. doi:10.1021/j100727a049.
- Liu, Xuesong; Li, Zejing; Tang, Jianguo; Yu, Bing; Cong, Hailin (9 September 2013). "Current status and future developments in preparation and application of colloidal crystals". Chemical Society Reviews. 42 (19): 7774–7800. doi:10.1039/C3CS60078E. ISSN 1460-4744. PMID 23836297.
- Frimmel, Fritz H.; Frank von der Kammer; Hans-Curt Flemming (2007). Colloidal transport in porous media (1 ed.). Springer. p. 292. ISBN 978-3-540-71338-8.
- Alonso, U.; T. Missana; A. Patelli; V. Rigato (2007). "Bentonite colloid diffusion through the host rock of a deep geological repository". Physics and Chemistry of the Earth, Parts A/B/C. 32 (1–7): 469–476. Bibcode:2007PCE....32..469A. doi:10.1016/j.pce.2006.04.021. ISSN 1474-7065.
- Voegelin, A.; Kretzschmar, R. (December 2002). "Stability and mobility of colloids in Opalinus Clay" (PDF). Technischer Bericht / NTB. Institute of Terrestrial Ecology, ETH Zürich. Nagra Technical Report 02-14.: 47. ISSN 1015-2636. Archived from the original (PDF) on 9 March 2009. Retrieved 22 February 2009.
- "Diffusion of colloids in compacted bentonite". Archived from the original on 4 March 2009. Retrieved 12 February 2009.
- Wold, Susanna; Trygve Eriksen (2007). "Diffusion of humic colloids in compacted bentonite". Physics and Chemistry of the Earth, Parts A/B/C. 32 (1–7): 477–484. Bibcode:2007PCE....32..477W. doi:10.1016/j.pce.2006.05.002. ISSN 1474-7065.
- R., Weil, Ray (11 October 2018). Elements of the nature and properties of soils. Brady, Nyle C. (Fourth ed.). New York, NY. ISBN 9780133254594. OCLC 1035317420.
- Martin, Gregory S. (19 April 2005). "An Update on Intravenous Fluids". Medscape. Medscape Infectious Diseases. Retrieved 6 July 2016.
- Blake, Heidi (3 March 2011). "Millions of surgery patients at risk in drug research fraud scandal". The Telegraph. UK. Archived from the original on 4 November 2011. Retrieved 4 November 2011.
- Berg, J.C. An Introduction to Interfaces and Colloids: The Bridge to Nanoscience. World Scientific Publishing Co., 2010, ISBN 981-4293-07-5
- Lyklema, J. Fundamentals of Interface and Colloid Science, Vol. 2, p. 3208, 1995
- Hunter, R.J. Foundations of Colloid Science, Oxford University Press, 1989
- Dukhin, S.S. & Derjaguin, B.V. Electrokinetic Phenomena, J. Wiley and Sons, 1974
- Russel, W.B., Saville, D.A. and Schowalter, W.R. Colloidal Dispersions, Cambridge, 1989 Cambridge University Press
- Kruyt, H.R. Colloid Science, Volume 1, Irreversible systems, Elsevier, 1959
- Dukhin, A.S. and Goetz, P.J. Ultrasound for characterizing colloids, Elsevier, 2002
- Rodil, Ma. Lourdes C., Chemistry The Central Science, 7th Ed. ISBN 0-13-533480-2
- Pieranski, P., Colloidal Crystals, Contemp. Phys., Vol. 24, p. 25 (1983)
- Sanders, J.V., Structure of Opal, Nature, Vol. 204, p. 1151, (1964);
- Darragh, P.J., et al., Scientific American, Vol. 234, p. 84, (1976)
- Luck, W. et al., Ber. Busenges Phys. Chem., Vol. 67, p. 84 (1963);
- Hiltner, P.A. and Krieger, I.M., Diffraction of Light by Ordered Suspensions, J. Phys. Chem., Vol. 73, p. 2306 (1969)
- Arora, A.K., Tata, B.V.R., Eds. Ordering & Phase Transitions in Charged Colloids Wiley, New York (1996)
- Sood, A.K. in Solid State Physics, Eds. Ehrenreich, H., Turnbull, D., Vol. 45, p. 1 (1991)
- Murray, C.A. and Grier, D.G., Colloidal Crystals, Amer. Scientist, Vol. 83, p. 238 (1995);
- Video Microscopy of Monodisperse Colloidal Systems, Annu. Rev. Phys. Chem., Vol. 47, p. 421 (1996)
- Tanaka, T., in Responsive Gels,Volume Transitions 1, Ed. Karl Dusek, Advances in Polymer Science, Vol.109, Springer Berlin (1993)