3D model (JSmol)
|Molar mass||196.1659 g mol−1|
|Melting point||212 °C (414 °F; 485 K)|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Silicon tetraazide is a thermally unstable binary compound of silicon and nitrogen with a nitrogen content of 85.7%. This high-energy compound combusts spontaneously and can only be studied in a solution  A further coordination to a six-fold coordinated structure like a hexaazido silicide [Si(N3)6]2−  or as an adduct with bicationic ligands Si(N3)4L2  will result in relatively stable, crystalline solids that can be handled at room temperature.
The reaction of silicon tetrachloride with an excess of sodium azide at room temperature in acetonitrile will result in the formation of sodium hexaazidosilicide which by adding ligands such as 2,2′-bipyridine and 1,10-phenanthroline will result in stable silicon tetraazide adducts  Other bases such as pyridine and tetramethylethylenediamine will not react with the hexaazido silicide ion.
Another preparation of a bis(triphenylphosphino)iminiumhexaazido silicide salt ((PPN)2Si(N3)6, [Ph3P=NPPh3][Si(N3)6]) is possible by conversion of bis(triphenylphosphino)iminium azide (PPNN3, [Ph3P=NPPh3]+N3−) with silicon tetrachloride in acetonitrile.
Silicon tetraazide is a white crystalline compound that will detonate at even 0 °C. The pure compound but also silicon chloride triazide and silicon dichloride diazide contaminated samples can without clear cause detonate spontaneously  The compound is susceptible to hydrolysis. It is soluble in diethylether and benzene.
The addition compound with 2,2′-bipyridine is much more stable. A melting point of 212 °C with a melting enthalpy of 110 J·g−1 is recorded. The DSC measurement shows at 265 °C a sharp exothermic reaction with an enthalpy of −2400 J·g−1. Similar results are found for the addition compound with 1,10-phenanthroline. As the hemiacetonitrile solvatated isolated compound expels solvent at 100 °C, and shows then in the DSC measurement from 240 °C onwards a strong exothermic reaction with a generated heat of 2300 J·g−1. The enthalpies are higher than that of sodium azide with −800 J·g−1, but still lower than the values encountered with classic explosives such as RDX with −4500 J·g−1. The addition compounds are stable in solution. It can be concluded from IR-spectroscopy and proton NMR data that no dissociation occurs in silicon tetraazide and 2,2'-bipyridine or for example 1,10-phenanthroline. The bis(triphenylphosphino)iminiumhexaazidosilicate salt ((PPN)2Si(N3)6) on the other hand is relatively stable. the compound melts at 214 °C and shows in the DSC measurement at 250 °C a reaction  One mass spectrometry coupled thermogravimetric analysis investigation indicated as reaction products nitrogen, silicon tetraazide and hydrazoic acid.
A practical application of free silicon tetraazide is unlikely due to the high instability. In solution the compound has potential uses as raw material for nitrogen-rich materials. One application as reagent in the manufacture of polyolefins has been patented. The stabilized adducts can serve as energetic compounds as a replacement for lead azide.
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- Gmelins Handbook of Inorganic Chemistry, 8th Edition, Silicon Supplement Volume B4, Springer-Verlag 1989, S. 46.
- Filippou, A.C.; Portius, P.; Schnakenburg, G.: The Hexaazidosilicate(IV) Ion: Synthesis, Properties, and Molecular Structure in J. Am. Chem. Soc. 124 (2002) S. 12396–12397, doi:10.1021/ja0273187
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Salts and covalent derivatives of the azide ion