In nuclear physics, the semi-empirical mass formula (SEMF) (sometimes also called Weizsäcker's formula, or the Bethe–Weizsäcker formula, or the Bethe–Weizsäcker mass formula to distinguish it from the Bethe–Weizsäcker process) is used to approximate the mass and various other properties of an atomic nucleus from its number of protons and neutrons. As the name suggests, it is based partly on theory and partly on empirical measurements. The theory is based on the liquid drop model proposed by George Gamow, which can account for most of the terms in the formula and gives rough estimates for the values of the coefficients. It was first formulated in 1935 by German physicist Carl Friedrich von Weizsäcker, and although refinements have been made to the coefficients over the years, the structure of the formula remains the same today.
The SEMF gives a good approximation for atomic masses and several other effects, but does not explain the appearance of magic numbers of protons and neutrons, and the extra binding-energy and measure of stability that are associated with these numbers of nucleons.
The liquid drop model and its analysis
The liquid drop model in nuclear physics treats the nucleus as a drop of incompressible nuclear fluid of very high density. It was first proposed by George Gamow and then developed by Niels Bohr and John Archibald Wheeler. The nucleus is made of nucleons (protons and neutrons), which are held together by the nuclear force (a residual effect of the strong force). This is very similar to the structure of a spherical liquid drop made of microscopic molecules. This is a crude model that does not explain all the properties of the nucleus, but does explain the spherical shape of most nuclei. It also helps to predict the nuclear binding energy and to assess how much is available for consumption.
Mathematical analysis of the theory delivers an equation which attempts to predict the binding energy of a nucleus in terms of the numbers of protons and neutrons it contains. This equation has five terms on its right hand side. These correspond to a volume term (due to the cohesive binding of all the nucleons by the nuclear force), a surface energy term, the electrostatic (Coulomb) mutual repulsion of the protons, an asymmetry term (derivable from the protons and neutrons occupying independent quantum momentum states) and a pairing term (partly derivable from the protons and neutrons occupying independent quantum spin states).
If we consider the sum of the following five types of energies, then the picture of a nucleus as a drop of incompressible liquid roughly accounts for the observed variation of binding energy of the nucleus:
Volume energy. When an assembly of nucleons of the same size is packed together into the smallest volume, each interior nucleon has a certain number of other nucleons in contact with it. So, this nuclear energy is proportional to the volume.
Surface energy. A nucleon at the surface of a nucleus interacts with fewer other nucleons than one in the interior of the nucleus and hence its binding energy is less. This surface energy term takes that into account and is therefore negative and is proportional to the surface area.
Coulomb Energy. The electric repulsion between each pair of protons in a nucleus contributes toward decreasing its binding energy.
Asymmetry energy (also called Pauli Energy). An energy associated with the Pauli exclusion principle. Were it not for the Coulomb energy, the most stable form of nuclear matter would have the same number of neutrons as protons, since unequal numbers of neutrons and protons imply filling higher energy levels for one type of particle, while leaving lower energy levels vacant for the other type.
Pairing energy. An energy which is a correction term that arises from the tendency of proton pairs and neutron pairs to occur. An even number of particles is more stable than an odd number.
The mass of an atomic nucleus is given by
where and are the rest mass of a proton and a neutron, respectively, and is the binding energy of the nucleus. The semi-empirical mass formula states that the binding energy will take the following form:
Each of the terms in this formula has a theoretical basis, as will be explained below. The coefficients , , , and a coefficient that appears in the formula for are determined empirically.
The term is known as the volume term. The volume of the nucleus is proportional to A, so this term is proportional to the volume, hence the name.
The basis for this term is the strong nuclear force. The strong force affects both protons and neutrons, and as expected, this term is independent of Z. Because the number of pairs that can be taken from A particles is , one might expect a term proportional to . However, the strong force has a very limited range, and a given nucleon may only interact strongly with its nearest neighbors and next nearest neighbors. Therefore, the number of pairs of particles that actually interact is roughly proportional to A, giving the volume term its form.
The coefficient is smaller than the binding energy possessed by the nucleons with respect to their neighbours (), which is of order of 40 MeV. This is because the larger the number of nucleons in the nucleus, the larger their kinetic energy is, due to the Pauli exclusion principle. If one treats the nucleus as a Fermi ball of nucleons, with equal numbers of protons and neutrons, then the total kinetic energy is , with the Fermi energy which is estimated as 28 MeV. Thus the expected value of in this model is , not far from the measured value.
The term is known as the surface term. This term, also based on the strong force, is a correction to the volume term.
The volume term suggests that each nucleon interacts with a constant number of nucleons, independent of A. While this is very nearly true for nucleons deep within the nucleus, those nucleons on the surface of the nucleus have fewer nearest neighbors, justifying this correction. This can also be thought of as a surface tension term, and indeed a similar mechanism creates surface tension in liquids.
If the volume of the nucleus is proportional to A, then the radius should be proportional to and the surface area to . This explains why the surface term is proportional to . It can also be deduced that should have a similar order of magnitude as .
The term or is known as the Coulomb or electrostatic term.
The basis for this term is the electrostatic repulsion between protons. To a very rough approximation, the nucleus can be considered a sphere of uniform charge density. The potential energy of such a charge distribution can be shown to be
where Q is the total charge and R is the radius of the sphere. Identifying Q with , and noting as above that the radius is proportional to , we get close to the form of the Coulomb term. However, because electrostatic repulsion will only exist for more than one proton, becomes . The value of can be approximately calculated using the equation above:
Quantum charge integers:
Solving by substitution:
Potential energy of charge distribution:
Electrostatic Coulomb constant:
The value of using the fine structure constant:
where is the fine structure constant and is the radius of a nucleus, giving to be approximately 1.25 femtometers. is the proton Compton radius and the proton mass. This gives an approximate theoretical value of 0.691 MeV, not far from the measured value.
The term or is known as the asymmetry term. Note that as , the parenthesized expression can be rewritten as . The form is used to keep the dependence on A explicit, as it will be important for a number of uses of the formula.
The theoretical justification for this term is more complex. The Pauli exclusion principle states that no two identical fermions can occupy exactly the same quantum state in an atom. At a given energy level, there are only finitely many quantum states available for particles. What this means in the nucleus is that as more particles are "added", these particles must occupy higher energy levels, increasing the total energy of the nucleus (and decreasing the binding energy). Note that this effect is not based on any of the fundamental forces (gravitational, electromagnetic, etc.), only the Pauli exclusion principle.
Protons and neutrons, being distinct types of particles, occupy different quantum states. One can think of two different "pools" of states, one for protons and one for neutrons. Now, for example, if there are significantly more neutrons than protons in a nucleus, some of the neutrons will be higher in energy than the available states in the proton pool. If we could move some particles from the neutron pool to the proton pool, in other words change some neutrons into protons, we would significantly decrease the energy. The imbalance between the number of protons and neutrons causes the energy to be higher than it needs to be, for a given number of nucleons. This is the basis for the asymmetry term.
The actual form of the asymmetry term can again be derived by modelling the nucleus as a Fermi ball of protons and neutrons. Its total kinetic energy is
where , are the numbers of protons and neutrons and , are their Fermi energies. Since the latter are proportional to and , respectively, one gets
- for some constant C.
The leading expansion in the difference is then
At the zeroth order expansion the kinetic energy is just the Fermi energy multiplied by . Thus we get
The first term contributes to the volume term in the semi-empirical mass formula, and the second term is minus the asymmetry term (remember the kinetic energy contributes to the total binding energy with a negative sign).
is 38 MeV, so calculating from the equation above, we get only half the measured value. The discrepancy is explained by our model not being accurate: nucleons in fact interact with each other, and are not spread evenly across the nucleus. For example, in the shell model, a proton and a neutron with overlapping wavefunctions will have a greater strong interaction between them and stronger binding energy. This makes it energetically favourable (i.e. having lower energy) for protons and neutrons to have the same quantum numbers (other than isospin), and thus increase the energy cost of asymmetry between them.
One can also understand the asymmetry term intuitively, as follows. It should be dependent on the absolute difference , and the form is simple and differentiable, which is important for certain applications of the formula. In addition, small differences between Z and N do not have a high energy cost. The A in the denominator reflects the fact that a given difference is less significant for larger values of A.
where is found empirically to have a value of about 1000 keV, slowly decreasing with mass number A. The dependence on mass number is commonly parametrized as
The value of the exponent kP is determined from experimental binding energy data. In the past its value was often assumed to be −3/4, but modern experimental data indicate that a value of −1/2 is nearer the mark:
- or .
Due to the Pauli exclusion principle the nucleus would have a lower energy if the number of protons with spin up were equal to the number of protons with spin down. This is also true for neutrons. Only if both Z and N are even can both protons and neutrons have equal numbers of spin up and spin down particles. This is a similar effect to the asymmetry term.
The factor is not easily explained theoretically. The Fermi ball calculation we have used above, based on the liquid drop model but neglecting interactions, will give an dependence, as in the asymmetry term. This means that the actual effect for large nuclei will be larger than expected by that model. This should be explained by the interactions between nucleons; For example, in the shell model, two protons with the same quantum numbers (other than spin) will have completely overlapping wavefunctions and will thus have greater strong interaction between them and stronger binding energy. This makes it energetically favourable (i.e. having lower energy) for protons to form pairs of opposite spin. The same is true for neutrons.
Calculating the coefficients
The coefficients are calculated by fitting to experimentally measured masses of nuclei. Their values can vary depending on how they are fitted to the data. Several examples are as shown below, with units of megaelectronvolts.
|Least-squares fit (1)||Least-squares fit (2)||Rohlf||Wapstra|
|exponent of A in δ0||−1/2||−3/4||−1/2||−3/4|
The formula does not consider the internal shell structure of the nucleus. The semi-empirical mass formula therefore provides a good fit to heavier nuclei, and a poor fit to very light nuclei, especially 4He. For light nuclei, it is usually better to use a model that takes this shell structure into account.
Examples for consequences of the formula
By maximizing Eb(A,Z) with respect to Z, we find the best neutrons to protons ratio N/Z for a given atomic weight A. We get
This is roughly 1 for light nuclei, but for heavy nuclei the ratio grows in good agreement with experiment.
By substituting the above value of Z back into Eb one obtains the binding energy as a function of the atomic weight, Eb(A). Maximizing Eb(A)/A with respect to A gives the nucleus which is most strongly bound, i.e. most stable. The value we get is A = 63 (copper), close to the measured values of A = 62 (nickel) and A = 58 (iron).
The liquid drop model also allows the computation of fission barriers for nuclei, which determine the stability of a nucleus against spontaneous fission. It was originally speculated that elements beyond atomic number 104 could not exist, as they would undergo fission with very short half-lives, though this formula did not consider stabilizing effects of closed nuclear shells. A modified formula considering shell effects reproduces known data and the predicted island of stability, though also suggests a limit to existence of superheavy nuclei beyond Z = 120 and N = 184.
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