A mononuclidic element or monotopic element is one of the 22 chemical elements that is found naturally on Earth essentially as a single nuclide (which may, or may not, be a stable nuclide). This single nuclide will have a characteristic atomic mass. Thus, the element's natural isotopic abundance is dominated either by one stable isotope or by one very long-lived isotope. There are 19 elements in the first category (which are both monoisotopic and mononuclidic), and 3 (bismuth, thorium and protactinium) in the second category (mononuclidic but not monoisotopic, since they have zero, not one, stable nuclides). A list of the 22 mononuclidic elements is given at the end of this article.
Of the 26 monoisotopic elements that, by definition, have only one stable isotope, there exist 7 (26 minus 19 = 7) which are nevertheless not considered mononuclidic, due to the presence of a significant fraction of a very long-lived (primordial) radioisotope occurring in their natural abundance. These elements are vanadium, rubidium, indium, lanthanum, europium, rhenium, and lutetium.
Use in metrology
Mononuclidic elements are of scientific importance because their atomic weights can be measured to high accuracy, since there is minimal uncertainty associated with the isotopic abundances present in a given sample. Another way of stating this, is that, for these elements, the standard atomic weight and atomic mass are the same.
In practice, only 11 of the mononuclidic elements are used in standard atomic weight metrology. These are aluminium, bismuth, caesium, cobalt, gold, manganese, phosphorus, scandium, sodium, terbium, and thorium.
In nuclear magnetic resonance spectroscopy (NMR), the three most sensitive stable nuclei are hydrogen-1 (1H), fluorine-19 (19F) and phosphorus-31 (31P). Fluorine and phosphorus are monoisotopic, with hydrogen nearly so. 1H NMR, 19F NMR and 31P NMR allow for identification and study of compounds containing these elements.
Contamination by unstable trace isotopes
Trace concentrations of unstable isotopes of some mononuclidic elements are found in natural samples. For example, beryllium-10 (10Be), with a half-life of 1.4 million years, is produced by cosmic rays in the Earth's upper atmosphere; iodine-129 (129I), with a half-life of 15.7 million years, is produced by various cosmogenic and nuclear mechanisms; caesium-137 (137Cs), with a half-life of 30 years, is generated by nuclear fission. Such isotopes are used in a variety of analytical and forensic applications.
Complete list of the 22 mononuclidic elements
|Element||Nuclide||Z (p)||N (n)||Isotopic mass (u)||Notes|
|fluorine||19F||9||10||18.998 403 2(5)|
- Primordial element
- Table of nuclides sorted by half-life
- Table of nuclides
- Isotope geochemistry
- List of elements by stability of isotopes
- Housecroft, C. E.; Sharpe, A. G. (2012). Inorganic Chemistry (4th ed.). Prentice Hall. p. 2. ISBN 978-0273742753.
- Until 2003, 209Bi was thought to be in the first category. It was then found to have a half-life of 1019 years, about a billion times the age of the universe. See Bismuth
- N. E. Holden, "Standard Atomic Weight Values for the Mononuclidic Elements - 2001," BNL-NCS-68362, Brookhaven National Laboratory (2001)
- IUPAC list of mononuclidics for metrology purposes