The planet Mars has two permanent polar ice caps. During a pole's winter, it lies in continuous darkness, chilling the surface and causing the deposition of 25–30% of the atmosphere into slabs of CO2 ice (dry ice). When the poles are again exposed to sunlight, the frozen CO2 sublimes. These seasonal actions transport large amounts of dust and water vapor, giving rise to Earth-like frost and large cirrus clouds.
The caps at both poles consist primarily of water ice. Frozen carbon dioxide accumulates as a comparatively thin layer about one metre thick on the north cap in the northern winter, while the south cap has a permanent dry ice cover about 8 m thick. The northern polar cap has a diameter of about 1000 km during the northern Mars summer, and contains about 1.6 million cubic km of ice, which if spread evenly on the cap would be 2 km thick. (This compares to a volume of 2.85 million cubic km (km3) for the Greenland ice sheet.) The southern polar cap has a diameter of 350 km and a thickness of 3 km. The total volume of ice in the south polar cap plus the adjacent layered deposits has also been estimated at 1.6 million cubic km. Both polar caps show spiral troughs, which recent analysis of SHARAD ice penetrating radar has shown are a result of roughly perpendicular katabatic winds that spiral due to the Coriolis Effect.
The seasonal frosting of some areas near the southern ice cap results in the formation of transparent 1 m thick slabs of dry ice above the ground. With the arrival of spring, sunlight warms the subsurface and pressure from subliming CO2 builds up under a slab, elevating and ultimately rupturing it. This leads to geyser-like eruptions of CO2 gas mixed with dark basaltic sand or dust. This process is rapid, observed happening in the space of a few days, weeks or months, a rate of change rather unusual in geology—especially for Mars. The gas rushing underneath a slab to the site of a geyser carves a spider-like pattern of radial channels under the ice.
In July 2018, Italian scientists reported the discovery of a subglacial lake on Mars, 1.5 km (0.93 mi) below the surface of the southern polar layered deposits (not under the visible permanent ice cap), and about 20 km (12 mi) across, the first known stable body of water on the planet.
Freezing of atmosphere
Research based on slight changes in the orbits of spacecraft around Mars over 16 years found that each winter, approximately 3 trillion to 4 trillion tons of carbon dioxide freezes out of the atmosphere onto the winter hemisphere polar cap. This represents 12 to 16 percent of the mass of the entire Martian atmosphere. These observations support predictions from the Mars Global Reference Atmospheric Model—2010.
Both polar caps show layered features, called polar-layered deposits, that result from seasonal ablation and accumulation of ice together with dust from Martian dust storms. Information about the past climate of Mars may be eventually revealed in these layers, just as tree ring patterns and ice core data do on Earth. Both polar caps also display grooved features, probably caused by wind flow patterns. The grooves are also influenced by the amount of dust. The more dust, the darker the surface. The darker the surface, the more melting. Dark surfaces absorb more light energy. There are other theories that attempt to explain the large grooves.
- Layers in northern ice cap, as seen by HiRISE under HiWish program
North polar cap
The bulk of the northern ice cap consists of water ice; it also has a thin seasonal veneer of dry ice, solid carbon dioxide. Each winter the ice cap grows by adding 1.5 to 2 m of dry ice. In summer, the dry ice sublimates (goes directly from a solid to a gas) into the atmosphere. Mars has seasons that are similar to Earth's, because its rotational axis has a tilt close to our own Earth's (25.19° for Mars, 23.44° for Earth).
During each year on Mars as much as a third of Mars' thin carbon dioxide (CO2) atmosphere "freezes out" during the winter in the northern and southern hemispheres. Scientists have even measured tiny changes in the gravity field of Mars due to the movement of carbon dioxide.
The ice cap in the north is of a lower altitude (base at -5000 m, top at -2000 m) than the one in the south (base at 1000 m, top at 3500 m). It is also warmer, so all the frozen carbon dioxide disappears each summer. The part of the cap that survives the summer is called the north residual cap and is made of water ice. This water ice is believed to be as much as three kilometers thick. The much thinner seasonal cap starts to form in the late summer to early fall when a variety of clouds form. Called the polar hood, the clouds drop precipitation which thickens the cap. The north polar cap is symmetrical around the pole and covers the surface down to about 60 degrees latitude. High resolution images taken with NASA's Mars Global Surveyor show that the northern polar cap is covered mainly by pits, cracks, small bumps and knobs that give it a cottage cheese look. The pits are spaced close together relative to the very different depressions in the south polar cap.
Both polar caps show layered features that result from seasonal melting and deposition of ice together with dust from Martian dust storms. These polar layered deposits lie under the permanent polar caps. Information about the past climate of Mars may be eventually revealed in these layers, just as tree ring patterns and ice core data do on Earth. Both polar caps also display grooved features, probably caused by wind flow patterns and sun angles, although there are several theories that have been advanced. The grooves are also influenced by the amount of dust. The more dust, the darker the surface. The darker the surface, the more melting. Dark surfaces absorb more light energy. One large valley, Chasma Boreale runs halfway across the cap. It is about 100 km wide and up to 2 km deep—that's deeper than Earth's Grand Canyon.
When the tilt or obliquity changes the size of the polar caps change. When the tilt is at its highest, the poles receive far more sunlight and for more hours each day. The extra sunlight causes the ice to melt, so much so that it could cover parts of the surface in 10 m of ice. Much evidence has been found for glaciers that probably formed when this tilt-induced climate change occurred.
Research reported in 2009 shows that the ice rich layers of the ice cap match models for Martian climate swings. NASA's Mars Reconnaissance Orbiter's radar instrument can measure the contrast in electrical properties between layers. The pattern of reflectivity reveals the pattern of material variations within the layers. Radar produced a cross-sectional view of the north-polar layered deposits of Mars. High-reflectivity zones, with multiple contrasting layers, alternate with zones of lower reflectivity. Patterns of how these two types of zones alternate can be correlated to models of changes in the tilt of Mars. Since the top zone of the north-polar layered deposits—the most recently deposited portion—is strongly radar-reflective, the researchers propose that such sections of high-contrast layering correspond to periods of relatively small swings in the planet's tilt because the Martian axis has not varied much recently. Dustier layers appear to be deposited during periods when the atmosphere is dustier.
Research, published in January 2010 using HiRISE images, says that understanding the layers is more complicated than was formerly believed. The brightness of the layers does not just depend on the amount of dust. The angle of the sun together with the angle of the spacecraft greatly affect the brightness seen by the camera. This angle depends on factors such as the shape of the trough wall and its orientation. Furthermore, the roughness of the surface can greatly change the albedo (amount of reflected light). In addition, many times what one is seeing is not a real layer, but a fresh covering of frost. All of these factors are influenced by the wind which can erode surfaces. The HiRISE camera did not reveal layers that were thinner than those seen by the Mars Global Surveyor. However, it did see more detail within layers.
Radar measurements of the north polar ice cap found the volume of water ice in the layered deposits of the cap was 821,000 cubic kilometers (197,000 cubic miles). That's equal to 30% of the Earth's Greenland ice sheet. (The layered deposits overlie an additional basal deposit of ice.) The radar is on board the Mars Reconnaissance Orbiter.
SHARAD radar data when combined to form a 3D model reveal buried craters. These may be used to date certain layers.
South polar cap
The south polar permanent cap is much smaller than the one in the north. It is 400 km in diameter, as compared to the 1100 km diameter of the northern cap. Each southern winter, the ice cap covers the surface to a latitude of 50°. Part of the ice cap consists of dry ice, solid carbon dioxide. Each winter the ice cap grows by adding 1.5 to 2 meters of dry ice from precipitation from a polar-hood of clouds. In summer, the dry ice sublimates (goes directly from a solid to a gas) into the atmosphere. During each year on Mars as much as a third of Mars' thin carbon dioxide (CO2) atmosphere "freezes out" during the winter in the northern and southern hemispheres. Scientists have even measured tiny changes in the gravity field of Mars due to the movement of carbon dioxide. In other words, the winter buildup of ice changes the gravity of the planet. Mars has seasons that are similar to Earth's because its rotational axis has a tilt close to our own Earth's (25.19° for Mars, 23.45° for Earth). The south polar cap is higher in altitude and colder than the one in the north.
The residual southern ice cap is displaced; that is, it is not centered on the south pole. However, the south seasonal cap is centered near the geographic pole. Studies have shown that the off center cap is caused by much more snow falling on one side than the other. On the western hemisphere side of the south pole a low pressure system forms because the winds are changed by the Hellas Basin. This system produces more snow. On the other side, there is less snow and more frost. Snow tends to reflect more sunlight in the summer, so not much melts or sublimates (Mars climate causes snow to go directly from a solid to a gas). Frost, on the other hand has a rougher surface and tends to trap more sunlight, resulting in more sublimation. In other words, areas with more of the rougher frost are warmer.
Research, published in April 2011, described a large deposit of frozen carbon dioxide near the south pole. Most of this deposit probably enters Mars' atmosphere when the planet's tilt increases. When this occurs, the atmosphere thickens, winds get stronger, and larger areas on the surface can support liquid water.  Analysis of data showed that if these deposits were all changed into gas, the atmospheric pressure on Mars would double. There are three layers of these deposits; each is capped with a 30-meter layer of water ice that prevents the CO2 from sublimating into the atmosphere. In sublimation a solid material goes directly into a gas phase. These three layers are linked to periods when the atmosphere collapsed when the climate changed.
A large field of eskers exist around the south pole, called the Dorsa Argentea Formation, it is believed to be the remains of a giant ice sheet. This large polar ice sheet is believed to have covered about 1.5 million square kilometers. That area is twice the area of the state of Texas.[circular reference]
Swiss cheese appearance
While the north polar cap of Mars has a flat, pitted surface resembling cottage cheese, the south polar cap has larger pits, troughs and flat mesas that give it a Swiss cheese appearance. The upper layer of the Martian south polar residual cap has been eroded into flat-topped mesas with circular depressions. Observations made by Mars Orbiter Camera in 2001 have shown that the scarps and pit walls of the south polar cap had retreated at an average rate of about 3 meters (10 feet) since 1999. In other words, they were retreating 3 meters per Mars year. In some places on the cap, the scarps retreat less than 3 meters a Mars year, and in others it can retreat as much as 8 meters (26 feet) per Martian year. Over time, south polar pits merge to become plains, mesas turn into buttes, and buttes vanish forever. The round shape is probably aided in its formation by the angle of the sun. In the summer, the sun moves around the sky, sometimes for 24 hours each day, just above the horizon. As a result, the walls of a round depression will receive more intense sunlight than the floor; the wall will melt far more than the floor. The walls melt and recede, while the floor remains the same.
Later research with the powerful HiRISE showed that the pits are in a 1-10 meter thick layer of dry ice that is sitting on a much larger water ice cap. Pits have been observed to begin with small areas along faint fractures. The circular pits have steep walls that work to focus sunlight, thereby increasing erosion. For a pit to develop a steep wall of about 10 cm and a length of over 5 meters in necessary.
The pictures below show why it is said the surface resembles Swiss cheese; one can also observe the differences over a two-year period.
Changes in south polar surface from 1999 to 2001, as seen by Mars Global Surveyor.
Starburst channels or spiders
Starburst channels are patterns of channels that radiate out into feathery extensions. They are caused by gas which escapes along with dust. The gas builds up beneath translucent ice as the temperature warms in the spring. Typically 500 meters wide and 1 meter deep, the spiders may undergo observable changes in just a few days. One model for understanding the formation of the spiders says that sunlight heats dust grains in the ice. The warm dust grains settle by melting through the ice while the holes are annealed behind them. As a result, the ice becomes fairly clear. Sunlight then reaches the dark bottom of the slab of ice and changes the solid carbon dioxide ice into a gas which flows toward higher regions that open to the surface. The gas rushes out carrying dark dust with it. Winds at the surface will blow the escaping gas and dust into dark fans that we observe with orbiting spacecraft. The physics of this model is similar to ideas put forth to explain dark plumes erupting from the surface of Triton.
Research, published in January 2010 using HiRISE images, found that some of the channels in spiders grow larger as they go uphill since gas is doing the erosion. The researchers also found that the gas flows to a crack that has occurred at a weak point in the ice. As soon as the sun rises above the horizon, gas from the spiders blows out dust which is blown by wind to form a dark fan shape. Some of the dust gets trapped in the channels. Eventually frost covers all the fans and channels until the next spring when the cycle repeats.
Wide view of plumes, as seen by HiRISE under HiWish program Many of the plumes show spiders when enlarged.
Chasma Australe, a major valley, cuts across the layered deposits in the South Polar cap. On the 90 E side, the deposits rest on a major basin, called Prometheus.
Some of the layers in the south pole also show polygonal fracturing in the form of rectangles. It is thought that the fractures were caused by the expansion and contraction of water ice below the surface.
Polar ice cap deuterium enrichment
Evidence that Mars once had enough water to create a global ocean at least 137 m deep has been obtained from measurement of the HDO to H2O ratio over the north polar cap. In March 2015, a team of scientists published results showing that the polar cap ice is about eight times as enriched with deuterium, heavy hydrogen, as water in Earth's oceans. This means that Mars has lost a volume of water 6.5 times as large as that stored in today's polar caps. The water for a time may have formed an ocean in the low-lying Vastitas Borealis and adjacent lowlands (Acidalia, Arcadia and Utopia planitiae). Had the water ever all been liquid and on the surface, it would have covered 20% of the planet and in places would have been almost a mile deep.
This international team used ESO’s Very Large Telescope, along with instruments at the W. M. Keck Observatory and the NASA Infrared Telescope Facility, to map out different isotopic forms of water in Mars’s atmosphere over a six-year period.
- Ice cap images
This HiRISE image shows layers running roughly up and down, with faint polygonal fracturing (mostly rectangular).
South polar layers, as seen by THEMIS.
Close-up of layers in wall of McMurdo crater, as seen by HiRISE.
Chasma Boreale, as seen by HiRISE.
Chasma Boreale channels, as seen by HiRISE.
- Carbon dioxide
- Climate of Mars
- Dorsa Argentea Formation
- Geyser (Mars)
- Mare Australe quadrangle
- Swiss cheese features
- Phoenix (spacecraft)
- http://seg.org/podcast/Post/4604/Episode-10-Remote-sensing-on-Mars Podcast describing the use of SHARAD radar data to explore the ice caps
- https://sharad.psi.edu/3D/movies/SHARAD_PB3D_depth_20161223.mp4 High-resolution movie showing the interior of the north polar ice cap in 3D, as determined with SHARAD radar data
- https://sharad.psi.edu/3D/movies/SHARAD_PA3D_depth_20170105.mp4 High-resolution movie showing the interior of the south polar ice cap in 3D, as determined with SHARAD radar data
- Mellon, J. T.; Feldman, W. C.; Prettyman, T. H. (2003). "The presence and stability of ground ice in the southern hemisphere of Mars". Icarus. 169 (2): 324–340. Bibcode:2004Icar..169..324M. doi:10.1016/j.icarus.2003.10.022.
- Hess, S.; Henry, R.; Tillman, J. (1979). "The seasonal variation of atmospheric pressure on Mars as affected by the south polar cap". Journal of Geophysical Research. 84: 2923–2927. Bibcode:1979JGR....84.2923H. doi:10.1029/JB084iB06p02923.
- Darling, David. "Mars, polar caps". Encyclopedia of Astrobiology, Astronomy, and Spaceflight. Retrieved 2007-02-26.
- "MIRA's Field Trips to the Stars Internet Education Program". Mira.or. Retrieved 2007-02-26.
- Carr, Michael H.; Head, James W. (2003). "Oceans on Mars: An assessment of the observational evidence and possible fate". Journal of Geophysical Research. 108 (5042): 24. Bibcode:2003JGRE..108.5042C. doi:10.1029/2002JE001963.
- Phillips, Tony. "Mars is Melting, Science at NASA". Archived from the original on 2007-02-24. Retrieved 2007-02-26.
- Plaut, J. J.; et al. (2007). "Subsurface Radar Sounding of the South Polar Layered Deposits of Mars". Science. 316 (5821): 92–5. Bibcode:2007Sci...316...92P. doi:10.1126/science.1139672. PMID 17363628.
- Smith, Isaac B.; Holt, J. W. (2010). "Onset and migration of spiral troughs on Mars revealed by orbital radar". Nature. 465 (4): 450–453. Bibcode:2010Natur.465..450S. doi:10.1038/nature09049. PMID 20505722.
- "Mystery Spirals on Mars Finally Explained". Space.com. 26 May 2010. Retrieved 2010-05-26.
- "NASA Findings Suggest Jets Bursting From Martian Ice Cap". Jet Propulsion Laboratory. NASA. August 16, 2006. Retrieved 2009-08-11.
- Kieffer, H. H. (2000). "Annual Punctuated CO2 Slab-ice and Jets on Mars" (PDF). Retrieved 2009-09-06.
- G. Portyankina, ed. (2006). "Simulations of Geyser-type Eruptions in Cryptic Region of Martian South" (PDF). Retrieved 2009-08-11.
- Kieffer, Hugh H.; Christensen, Philip R.; Titus, Timothy N. (May 30, 2006). "CO2 jets formed by sublimation beneath translucent slab ice in Mars' seasonal south polar ice cap". Nature. 442 (7104): 793–796. Bibcode:2006Natur.442..793K. doi:10.1038/nature04945. PMID 16915284.
- Halton, Mary (July 25, 2018). "Liquid water 'lake' revealed on Mars". BBC News. Retrieved July 26, 2018.
- Orosei, R.; Lauro, S. E.; Pettinelli, E.; Cicchetti, A.; Coradini, M.; et al. (2018). "Radar evidence of subglacial liquid water on Mars". Science: eaar7268. doi:10.1126/science.aar7268. hdl:11573/1148029. PMID 30045881.
- Steigerwald, Bill (March 2016). "New gravity map gives best view yet inside Mars". NASA/Goddard Space Flight Center. Sciencedaily.com. Retrieved 2016-10-03.
- Genova, Antonio; Goossens, Sander; et al. (July 2016), "Seasonal and static gravity field of Mars from MGS, Mars Odyssey and MRO radio science", Icarus, 272: 228–245, Bibcode:2016Icar..272..228G, doi:10.1016/j.icarus.2016.02.050
- Barlow, Nadine G. (2008). Mars: an introduction to its interior, surface and atmosphere. Cambridge, UK: Cambridge University Press. pp. [, page , needed], . ISBN 978-0-521-85226-5.
- "Laser Altimeter Provides First Measurements of Seasonal Snow Depth On Mars". Goddard Space Flight Center. NASA. 6 December 2001. Archived from the original on 2009-07-12. Retrieved 2018-01-19.
- Faure, Gunter; Mensing, Teresa M. (2007-05-04). Introduction to Planetary Science: The Geological Perspective. Springer Science & Business Media. ISBN 9781402055447.
- Fishbaugh, K. (2001). "Comparison of the North and South Polar Caps of Mars: New Observations from MOLA Data and Discussion of Some Outstanding Questions". Icarus. 154 (1): 145–161. Bibcode:2001Icar..154..145F. doi:10.1006/icar.2001.6666.
- Taylor, Fredric W. (2009-12-10). The Scientific Exploration of Mars. ISBN 978-0-521-82956-4.
- ISBN 978-0-521-85226-5
- Bell, Jim (2008-06-05). The Martian Surface: Composition, Mineralogy and Physical Properties. ISBN 978-0-521-86698-9.
- "Radar Map of Buried Mars Layers Matches Climate Cycles". Jet Propulsion Lab. 2009-09-22. Retrieved 2018-07-10.
- Putzig, N. E.; Phillips, R. J.; Campbell, B. A.; Holt, J. W.; Plaut, J. J.; Carter, L. M.; Egan, A. F.; Bernardini, F.; Safaeinili, A.; Seu, R. (2009). "Subsurface structure of Planum Boreum from Mars Reconnaissance Orbiter Shallow Radar soundings". Icarus. 204 (2): 443–457. doi:10.1016/j.icarus.2009.07.034.
- Foss, F. J.; Putzig, N. E.; Campbell, B. A.; Phillips, R. J. (2017). "3D imaging of Mars' polar ice caps using orbital radar data". The Leading Edge. 36 (1): 43–57. doi:10.1190/tle36010043.1. PMC 5791158. PMID 29400351.
- Fishbaugh, K. E.; Byrne, S.; Herkenhoff, K. E.; Kirk, R. L.; Fortezzo, C.; Russell, P. S.; McEwen, A. (January 2010). "Evaluating the meaning of "layer" in the martian north polar layered deposits and the impact on the climate connection". Icarus. 205 (1): 269–282. Bibcode:2010Icar..205..269F. doi:10.1016/j.icarus.2009.04.011.
- Hansen, C.J.; Thomas, N.; Portyankina, G.; McEwen, A.; Becker, T.; Byrne, S.; Herkenhoff, K.; Kieffer, H.; Mellon, M. (2010). "HiRISE observations of gas sublimation-driven activity in Mars' southern polar regions: I. Erosion of the surface". Icarus. 205 (1): 283–295. Bibcode:2010Icar..205..283H. doi:10.1016/j.icarus.2009.07.021.
- Phillips, R., et al. 2011. Massive CO2 ice deposits sequestered in the south polar layered deposits of Mars. Science: 332, 638-841
- Bierson, C., et al. 2016. Stratigraphy and evolution of the buried CO2 depositin the Martian south polar cap. Geophysical Research Letters: 43, 4172-4179
- Head, J, S. Pratt. 2001. Extensive Hesperian-aged south polar ice sheet on Mars: Evidence for massive melting and retreat, and lateral flow and pending of meltwater. J. Geophys. Res.-Planet, 106 (E6), 12275-12299.
- List of U.S. states and territories by area
- Scanlon, K., et al. 2018. Icarus: 299, 339-363.
- Thomas,P., M. Malin, P. James, B. Cantor, R. Williams, P. Gierasch South polar residual cap of Mars: features, stratigraphy, and changes Icarus, 174 (2 SPEC. ISS.). 2005. pp. 535–559. http://doi.org/10.1016/j.icarus.2004.07.028
- Thomas, P., P. James, W. Calvin, R. Haberle, M. Malin. 2009. Residual south polar cap of Mars: stratigraphy, history, and implications of recent changes Icarus: 203, 352–375 http://doi.org/10.1016/j.icarus.2009.05.014
- Thomas, P., W.Calvin, P. Gierasch, R. Haberle, P. James, S. Sholes. 2013. Time scales of erosion and deposition recorded in the residual south polar cap of mars Icarus: 225: 923–932 http://doi.org/10.1016/j.icarus.2012.08.038
- Thomas, P., W. Calvin, B. Cantor, R. Haberle, P. James, S. Lee. 2016. Mass balance of Mars’ residual south polar cap from CTX images and other data Icarus: 268, 118–130 http://doi.org/10.1016/j.icarus.2015.12.038
- Hartmann, W. 2003. A Traveler's Guide to Mars. Workman Publishing. NY NY.
- Buhler, Peter, Andrew Ingersoll, Bethany Ehlmann, Caleb Fassett, James Head. 2017. How the martian residual south polar cap develops quasi-circular and heart-shaped pits, troughs, and moats. Icarus: 286, 69-9.
- Hansen, C, A. McEwen and HiRISE Team. December 2007. AGU Press Conference Spring at the South Pole of Mars.
- Kieffer, HH; Christensen, PR; Titus, TN (2006). "CO2 jets formed by sublimation beneath translucent slab ice in Mars'seasonal south polar ice cap". Nature. 442 (7104): 793–796. Bibcode:2006Natur.442..793K. doi:10.1038/nature04945. PMID 16915284.
- Soderblom, L. A.; Kieffer, S. W.; Becker, T. L.; Brown, R. H.; Cook, A. F.; Hansen, C. J.; Johnson, T. V.; Kirk, R. L.; Shoemaker, E. M. (1990). "Triton's geyser-like plumes: discovery and basic characterizations". Science. 250 (4979): 410–415. Bibcode:1990Sci...250..410S. doi:10.1126/science.250.4979.410. PMID 17793016.
- Thomas, N.; Hansen, C.J.; Portyankina, G.; Russell, P.S. (2010). "HiRISE observations of gas sublimation-driven activity in Mars' southern polar regions: II. Surficial deposits and their origins". Icarus. 205 (1): 296–310. Bibcode:2010Icar..205..296T. doi:10.1016/j.icarus.2009.05.030.
- Carr, Michael H. (2006). The Surface of Mars. Cambridge University Press. p. [page needed]. ISBN 978-0-521-87201-0.
- European Southern Observatory (2015-03-05). "Mars: The planet that lost an ocean's worth of water". ScienceDaily. Archived from the original on 2015-03-10. Retrieved 2015-03-10.
- Villanueva, G. L.; Mumma, M. J.; Novak, R. E.; Käufl, H. U.; Hartogh, P.; Encrenaz, T.; Tokunaga, A.; Khayat, A.; Smith, M. D. (2015-03-05). "Strong water isotopic anomalies in the martian atmosphere: Probing current and ancient reservoirs". Science. 348 (6231): 218–221. Bibcode:2015Sci...348..218V. doi:10.1126/science.aaa3630. PMID 25745065.