In nuclear physics, a magic number is a number of nucleons (either protons or neutrons, separately) such that they are arranged into complete shells within the atomic nucleus. The seven most widely recognized magic numbers as of 2019 are 2, 8, 20, 28, 50, 82, and 126 (sequence A018226 in the OEIS). For protons, this corresponds to the elements helium, oxygen, calcium, nickel, tin, lead and the hypothetical unbihexium, although 126 is so far only known to be a magic number for neutrons. Atomic nuclei consisting of such a magic number of nucleons have a higher average binding energy per nucleon than one would expect based upon predictions such as the semi-empirical mass formula and are hence more stable against nuclear decay.
The unusual stability of isotopes having magic numbers means that transuranium elements could theoretically be created with extremely large nuclei and yet not be subject to the extremely rapid radioactive decay normally associated with high atomic numbers. Large isotopes with magic numbers of nucleons are said to exist in an island of stability. Unlike the magic numbers 2–126, which are realized in spherical nuclei, theoretical calculations predict that nuclei in the island of stability are deformed. Before this was realized, higher magic numbers, such as 184, 258, 350, and 462 (sequence A033547 in the OEIS), were predicted based on simple calculations that assumed spherical shapes: these are generated by the formula (see binomial coefficient). It is now believed that the sequence of spherical magic numbers cannot be extended in this way. Further predicted magic numbers are 114, 122, 124, and 164 for protons as well as 184, 196, 236, and 318 for neutrons.
Origin of the term
According to Steven A. Moszkowski (a student of Maria Goeppert-Mayer), the term "magic number" was coined by Eugene Wigner: "Wigner too believed in the liquid drop model, but he recognized, from the work of Maria Mayer, the very strong evidence for the closed shells. It seemed a little like magic to him, and that is how the words 'Magic Numbers' were coined."
Nuclei which have neutron number and proton (atomic) numbers each equal to one of the magic numbers are called "doubly magic", and are especially stable against decay. The known doubly magic isotopes are helium-4, helium-10, oxygen-16, calcium-40, calcium-48, nickel-48, nickel-56, nickel-78, tin-100, tin-132 and lead-208. However, only the first, third, fourth, and last of these doubly magic nuclides are completely stable, although calcium-48 is extremely long-lived and therefore naturally occurring, disintegrating only by a very inefficient double beta minus decay process.
Doubly-magic effects may allow existence of stable isotopes which otherwise would not have been expected. An example is calcium-40, with 20 neutrons and 20 protons, which is the heaviest stable isotope made of the same number of protons and neutrons. Both calcium-48 and nickel-48 are doubly magic because calcium-48 has 20 protons and 28 neutrons while nickel-48 has 28 protons and 20 neutrons. Calcium-48 is very neutron-rich for such a light element, but like calcium-40, it is stabilized by being doubly magic.
Magic effects can keep unstable nuclides from decaying as rapidly as would otherwise be expected. For example, the nuclides tin-100 and tin-132 are examples of doubly magic isotopes of tin that are unstable, and represent endpoints beyond which stability drops off rapidly. Nickel-48, discovered in 1999, is the most proton-rich nuclide known beyond helium-3. At the other extreme, nickel-78 is also doubly magic, with 28 protons and 50 neutrons, a ratio observed only in much heavier elements apart from tritium with one proton and two neutrons (78Ni: 28/50 = 0.56; 238U: 92/146 = 0.63).
In December 2006, hassium-270, with 108 protons and 162 neutrons, was discovered by an international team of scientists led by the Technical University of Munich, having a half-life of 9 seconds. Hassium-270 evidently forms part of an island of stability, and may even be doubly magic due to the deformed (American football- or rugby ball-like) shape of this nucleus.
Although Z = 92 and N = 164 are not magic numbers, the undiscovered neutron-rich nucleus uranium-256 may be doubly magic and spherical due to the difference in size between low- and high-angular momentum orbitals, which alters the shape of the nuclear potential.
Magic numbers are typically obtained by empirical studies; if the form of the nuclear potential is known, then the Schrödinger equation can be solved for the motion of nucleons and energy levels determined. Nuclear shells are said to occur when the separation between energy levels is significantly greater than the local mean separation.
In the shell model for the nucleus, magic numbers are the numbers of nucleons at which a shell is filled. For instance, the magic number 8 occurs when the 1s1/2, 1p3/2, 1p1/2 energy levels are filled, as there is a large energy gap between the 1p1/2 and the next highest 1d5/2 energy levels.
The atomic analog to nuclear magic numbers are those numbers of electrons leading to discontinuities in the ionization energy. These occur for the noble gases helium, neon, argon, krypton, xenon, radon and oganesson. Hence, the "atomic magic numbers" are 2, 10, 18, 36, 54, 86 and 118. As with the nuclear magic numbers, these are expected to be changed in the superheavy region due to spin–orbit coupling effects affecting subshell energy levels. Hence copernicium (112) and flerovium (114) are expected to be more inert than oganesson (118), and the next noble gas after these is expected to occur at element 172 rather than 168 (which would continue the pattern).
In 2010, an alternative explanation of magic numbers was given in terms of symmetry considerations. Based on the fractional extension of the standard rotation group, the ground state properties (including the magic numbers) for metallic clusters and nuclei were simultaneously determined analytically. A specific potential term is not necessary in this model.
- Kratz, J. V. (5 September 2011). The Impact of Superheavy Elements on the Chemical and Physical Sciences (PDF). 4th International Conference on the Chemistry and Physics of the Transactinide Elements. Retrieved 27 August 2013.
- "Nuclear scientists eye future landfall on a second 'island of stability'".
- Grumann, Jens; Mosel, Ulrich; Fink, Bernd; Greiner, Walter (1969). "Investigation of the stability of superheavy nuclei aroundZ=114 andZ=164". Zeitschrift für Physik. 228 (5): 371–386. Bibcode:1969ZPhy..228..371G. doi:10.1007/BF01406719.
- This reminiscence, from a talk by Moszkowski presented at the APS meeting in Indianapolis, May 4, 1996, is mentioned by Georges Audi in the paper "The History of Nuclidic Masses and of their Evaluation" (arXiv 2006)
- "What is Stable Nuclei - Unstable Nuclei - Definition". Periodic Table. 2019-05-22. Retrieved 2019-12-22.
- Nave, C. R. (1989). "The Most Tightly Bound Nuclei". HyperPhysics. 57 (6): 552. Bibcode:1989AmJPh..57..552S. doi:10.1119/1.15970.
- W., P. (October 23, 1999). "Twice-magic metal makes its debut - isotope of nickel". Science News. Archived from the original on May 24, 2012. Retrieved 2006-09-29.
- "Tests confirm nickel-78 is a 'doubly magic' isotope". Phys.org. September 5, 2014. Retrieved 2014-09-09.
- Audi, G.; Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S. (2017). "The NUBASE2016 evaluation of nuclear properties" (PDF). Chinese Physics C. 41 (3): 030001–134. Bibcode:2017ChPhC..41c0001A. doi:10.1088/1674-1137/41/3/030001.
- Mason Inman (2006-12-14). "A Nuclear Magic Trick". Physical Review Focus. 18. Retrieved 2006-12-25.
- Dvorak, J.; Brüchle, W.; Chelnokov, M.; Dressler, R.; Düllmann, Ch. E.; Eberhardt, K.; Gorshkov, V.; Jäger, E.; Krücken, R.; Kuznetsov, A.; Nagame, Y.; Nebel, F.; Novackova, Z.; Qin, Z.; Schädel, M.; Schausten, B.; Schimpf, E.; Semchenkov, A.; Thörle, P.; Türler, A.; Wegrzecki, M.; Wierczinski, B.; Yakushev, A.; Yeremin, A. (2006). "Doubly Magic Nucleus 108270Hs162". Physical Review Letters. 97 (24): 242501. Bibcode:2006PhRvL..97x2501D. doi:10.1103/PhysRevLett.97.242501. PMID 17280272.
- Koura, H.; Chiba, S. (2013). "Single-Particle Levels of Spherical Nuclei in the Superheavy and Extremely Superheavy Mass Region". Journal of the Physical Society of Japan. 82: 014201. doi:10.7566/JPSJ.82.014201.
- Herrmann, Richard (2010). "Higher dimensional mixed fractional rotation groups as a basis for dynamic symmetries generating the spectrum of the deformed Nilsson-oscillator". Physica A. 389 (4): 693–704. arXiv:0806.2300. Bibcode:2010PhyA..389..693H. doi:10.1016/j.physa.2009.11.016.
- Herrmann, Richard (2010). "Fractional phase transition in medium size metal clusters and some remarks on magic numbers in gravitationally and weakly bound clusters". Physica A. 389 (16): 3307–3315. arXiv:0907.1953. Bibcode:2010PhyA..389.3307H. doi:10.1016/j.physa.2010.03.033.
- Nave, C. R. "Shell Model of Nucleus". HyperPhysics.
- OEIS sequence A018226 (Magic numbers of nucleons: nuclei with one of these numbers of either protons or neutrons are more stable against nuclear decay)
- Scerri, Eric (2007). The Periodic Table, Its Story and Its Significance. Oxford University Press. ISBN 978-0-19-530573-9. see chapter 10 especially.
- Moskowitz, Clara. "New magic number "inside atoms" discovered". Scientific American.
- Watkins, Thayer. "A Nearly Complete Explanation of the Nuclear Magic Numbers".