In chemistry, a group (also known as a family) is a column of elements in the periodic table of the chemical elements. There are 18 numbered groups in the periodic table, and the f-block columns (between groups 3 and 4) are not numbered. The elements in a group have similar physical or chemical characteristics of the outermost electron shells of their atoms (i.e., the same core charge), as most chemical properties are dominated by the orbital location of the outermost electron.
There are three systems of group numbering for the groups, that often assign the same number to different groups. The modern numbering "group 1" to "group 18" has been recommended by the International Union of Pure and Applied Chemistry (IUPAC) since about 1990. It replaces two older incompatible naming schemes, used by the Chemical Abstract Service (CAS, more popular in the U. S.), and by IUPAC before 1990 (more popular in Europe).
Groups may also be identified by their topmost element or have a specific name. For example, group 16 is variously described as the "oxygen group" and as the "chalcogens". However, iron group usually does not mean "group 8". In chemistry it may mean either iron, cobalt, and nickel, or some other set of elements with similar chemical properties. In astrophysics and nuclear physics, it usually means those three plus chromium and manganese.
|Name by element||Trivial name
(*=IUPAC recommended name)
|Group 1||IA||IA||lithium family||alkali metals*|
|Group 2||IIA||IIA||beryllium family||alkaline earth metals*|
|Group 3||IIIA||IIIB||scandium family|
|Group 4||IVA||IVB||titanium family|
|Group 5||VA||VB||vanadium family|
|Group 6||VIA||VIB||chromium family|
|Group 7||VIIA||VIIB||manganese family|
|Group 8||VIII||VIIIB||iron family|
|Group 9||VIII||VIIIB||cobalt family|
|Group 10||VIII||VIIIB||nickel family|
|Group 11||IB||IB||copper family||coinage metals|
|Group 12||IIB||IIB||zinc family|
|Group 13||IIIB||IIIA||boron family||triels||triels from Greek tri (three, III)|
|Group 14||IVB||IVA||carbon family||tetrels||tetrels from Greek tetra (four, IV)|
|Group 15||VB||VA||nitrogen family||pentels, pnictogens*||pentels from Greek penta (five, V)|
|Group 16||VIB||VIA||oxygen family||chalcogens*|
|Group 17||VIIB||VIIA||fluorine family||halogens*|
|Group 18||0||VIIIA||helium family or neon family||noble gases*|
Some other names have been proposed and used without gaining wide acceptance: "volatile metals" for group 12; "icosagens" for group 13; "crystallogens", "adamantogens", and "merylides" for group 14; and "aerogens" for group 18.
CAS and old IUPAC numbering (A/B)
Two earlier group number systems exist: CAS (Chemical Abstracts Service) and old IUPAC. Both use numerals (Arabic or Roman) and letters A and B. Both systems agree on the numbers. The numbers indicate approximately the highest oxidation number of the elements in that group, and so indicate similar chemistry with other elements with the same numeral. The number proceeds in a linearly increasing fashion for the most part, once on the left of the table, and once on the right (see List of oxidation states of the elements), with some irregularities in the transition metals. However, the two systems use the letters differently. For example, potassium (K) has one valence electron. Therefore, it is located in group 1. Calcium (Ca) is in group 2, for it contains two valence electrons.
In the old IUPAC system the letters A and B were designated to the left (A) and right (B) part of the table, while in the CAS system the letters A and B are designated to main group elements (A) and transition elements (B). The old IUPAC system was frequently used in Europe, while the CAS is most common in America. The new IUPAC scheme was developed to replace both systems as they confusingly used the same names to mean different things. The new system simply numbers the groups increasingly from left to right on the standard periodic table. The IUPAC proposal was first circulated in 1985 for public comments, and was later included as part of the 1990 edition of the Nomenclature of Inorganic Chemistry.
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- Leigh, G. J. Nomenclature of Inorganic Chemistry: Recommendations 1990. Blackwell Science, 1990. ISBN 0-632-02494-1.
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